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When you do rietveld refinement of your own sample, Follow the Rietveld Refinement Steps
Rietveld refinement of dual (two, multi and mixed) phase XRD: GSAS-2
Part-II : Fundamentals of Rietveld Refinement with example CoRuMnSi material via FullProf Software
Rietveld refinement of x-ray diffraction data using gsas-2